Kvalifikáciu na VC Španielska 2010 vyhral Mark Webber, vedľa neho sa na štart postaví jeho kolega Sebastian Vettel. Red Bully v kvalifikácii deklasovali ostatných jazdcov, tretí Hamilton na nich stratil 0,829 s!
Výsledky kvalifikácie na VC Španielska:
| 1 | Mark Webber | RBR-Renault | 1:21,412 | 1:20,655 | 1:19,995 | |
| 2 | Sebastian Vettel | RBR-Renault | 1:21,680 | 1:20,772 | 1:20,101 | 0,106 |
| 3 | Lewis Hamilton | McLaren-Mercedes | 1:21,723 | 1:21,415 | 1:20,829 | 0,834 |
| 4 | Fernando Alonso | Ferrari | 1:21,957 | 1:21,549 | 1:20,937 | 0,942 |
| 5 | Jenson Button | McLaren-Mercedes | 1:21,915 | 1:21,168 | 1:20,991 | 0,996 |
| 6 | Michael Schumacher | Mercedes GP | 1:22,528 | 1:21,557 | 1:21,294 | 1,299 |
| 7 | Robert Kubica | Renault | 1:22,488 | 1:21,599 | 1:21,353 | 1,358 |
| 8 | Nico Rosberg | Mercedes GP | 1:22,419 | 1:21,867 | 1:21,408 | 1,413 |
| 9 | Felipe Massa | Ferrari | 1:22,564 | 1:21,841 | 1:21,585 | 1,590 |
| 10 | Kamui Kobayashi | BMW Sauber-Ferrari | 1:22,577 | 1:21,725 | 1:21,984 | 1,989 |
| 11 | Adrian Sutil | Force India-Mercedes | 1:22,628 | 1:21,985 | ||
| 12 | Pedro de la Rosa | BMW Sauber-Ferrari | 1:22,211 | 1:22,026 | ||
| 13 | Nico Hulkenberg | Williams-Cosworth | 1:22,857 | 1:22,131 | ||
| 14 | Vitaly Petrov | Renault | 1:22,976 | 1:22,139 | ||
| 15 | Sebastien Buemi | STR-Ferrari | 1:22,699 | 1:22,191 | ||
| 16 | Jaime Alguersuari | STR-Ferrari | 1:22,593 | 1:22,207 | ||
| 17 | Vitantonio Liuzzi | Force India-Mercedes | 1:23,084 | 1:22,854 | ||
| 18 | Rubens Barrichello | Williams-Cosworth | 1:23,125 | |||
| 19 | Jarno Trulli | Lotus-Cosworth | 1:24,674 | |||
| 20 | Heikki Kovalainen | Lotus-Cosworth | 1:24,748 | |||
| 21 | Timo Glock | Virgin-Cosworth | 1:25,475 | |||
| 22 | Lucas di Grassi | Virgin-Cosworth | 1:25,556 | |||
| 23 | Karun Chandhok | HRT-Cosworth | 1:26,750 | |||
| 24 | Bruno Senna | HRT-Cosworth | 1:27,122 |
